超支化聚合物是一类高度支化的三维大分子,因其独特的物理性质、化学特性及潜在的应用价值受到广泛关注。综述了超支化聚合物的主要合成方法如单-单体法(SMM)、双单体法(DMM)和其他合成方法,并阐述了超支化聚合物在金属纳米粒子稳定剂、涂料、药物载体、环境修复和石油开采等领域的应用,最后对超支化聚合物在今后的研究方向进行了分析和展望。
Hyperbranched polymers are highly branched three-dimensional macromolecules which have been attracting extensive attention due to their unique physical and chemical properties.The main methods for synthesis of hyperbranched polymers including single-monomer methodology (SMM),double-monomer methodology (DMM),and some other methodologies were summarized.Hyperbranched polymers have been widely applied on various fields such as stabilizer of metal nanoparticles,coatings,drug delivery,environmental remediation,and oil exploration.Finally,the research direction of hyperbranched polymers in the future was also analyzed and prospected.
[1] Flory P J.Molecular size distribution in three dimensional polymers Ⅵ.branched polymers containing A-R-Bf-1 type units[J].Journal of the American Chemical Society,1952,74(11):2718-2723.
[2] Zheng Y,Li S,Weng Z,et al.Hyperbranched polymers:advances from synthesis to applications[J].Chemical Society Reviews,2015,44(12):4091-4130.
[3] Chen S,Xu Z,Zhang D.Synthesis and application of epoxy-ended hyperbranched polymers[J].Chemical Engineering Journal,2018,343:283-302.
[4] Wu W,Tang R,Li Q,et al.Functional hyperbranched polymers with advanced optical,electrical and magnetic properties[J].Chemical Society Reviews,2015,44(12):3997-4022.
[5] Wang Y,Li W,Liu C,et al.Synthesis of hyperbranched poly(ester amide)s and their application in polycarbonate as rheological modification agent[J].Acta Polymerica Sinica,2017,(8):1304-1311.
[6] 沈燕宇,何桂金,郭永胜,等.超支化聚合物作为金属纳米粒子稳定剂的研究进展[J].石油学报(石油加工),2017,33(4):605-618.
[7] Wang D,Jin Y,Zhu X,et al.Synthesis and applications of stimuli-responsive hyperbranched polymers[J].Progress In Polymer Science,2017,64:114-153.
[8] Kim Y H,Webster O W.Hyperbranched polyphenylenes[J].Macromolecules,1992,25(21):5561-5572.
[9] Testud B,Pintori D,Grau E,et al.Hyperbranched polyesters by polycondensation of fatty acid-based AB(n)-type monomers[J].Green Chemistry,2017,19(1):259-269.
[10] 钱凯,秦冬玲,徐异峰,等.端羧基超支化聚酰胺阻垢剂的合成研究[J].现代化工,2018,38(2):127-131.
[11] Fréchet J M J,Henmi M,Gitsov I,et al.Self-condensing vinyl polymerization:an approach to dendritic materials[J].Science,1995,269:1080-1083.
[12] Liang H,Li X,Xiong L,et al.Synthesis and characterization of titania nanoparticles functionalized with hyperbranched polymer via self-condensing vinyl polymerization[J].Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry,2013,43(8):1034-1039.
[13] Bektas S,Ciftci M,Yagci Y.Hyperbranched polymers by visible light induced self-condensing vinyl polymerization and their modifications[J].Macromolecules,2013,46(17):6751-6757.
[14] 夏丽,周志平.SiO2多臂星型超支化嵌段共聚物复合材料的制备与表征[J].功能材料,2014,45(2):90-94.
[15] 王碧云.自缩合乙烯基聚合法合成超支化聚合物[J].科技创新与应用,2017(9):56.
[16] Suzuki M,Ii A,Saegusa T.Multibranching polymerization:palladium-catalyzed ring-opening polymerization of cyclic carbamate to produce hyperbranched dendritic polyamine[J].Macromolecules,1992,25(25):7071-7072.
[17] Parzuchowski P G,Stefańska M,Swiderska A,et al.Hyperbranched polyglycerols containing amine groups-synthesis,characterization and carbon dioxide capture[J].Journal of CO2 Utilization,2018,27:145-160.
[18] Aynali F,Doganci E,Doruk T,et al.Synthesis and characterization of antimicrobial polylactide via ring-opening polymerization and click chemistry methods[J].Polymer International,2019,68(3):385-393.
[19] Chang H T,Fréchet J M J.Proton-transfer polymerization:a new approach to hyperbranched polymers[J].Journal of the American Chemical Society,1999,121(10):2313-2314.
[20] 靳奇峰,陈欣,薛蕾,等.新型超支化环氧丙烯酸酯的合成及表征[J].山东化工,2015,44(5):861-864.
[21] Kadokawa J,Kaneko Y,Yamada S,et al.Synthesis of hyperbranched polymers via proton-transfer polymerization of acrylate monomer containing two hydroxy groups[J].Macromolecular Rapid Communications,2000,21(7):362-368.
[22] Emrick T,Chang H T,Frechet J M J.An A2+ B3 approach to hyperbranched aliphatic polyethers containing chain end epoxy substituents[J].Macromolecules,1999,32(19):6380-6382.
[23] 孙凤霞,彭夏雨,康立超,等.超支化聚合物合成方法概述[J].热固性树脂,2015,(3):49-54.
[24] 田军,张博晓,肖利吉,等.超支化聚合物合成的研究进展[J].粘接,2016(10):61-67.
[25] Sundararajan S,Samui A B,Kulkarni P S.Synthesis and characterization of poly(ethylene glycol) (PEG) based hyperbranched polyurethanes as thermal energy storage materials[J].Thermochimica Acta,2017,650:114-122.
[26] Wei Q,Pötzsch R,Liu X,et al.Hyperbranched polymers with high transparency and inherent high refractive index for application in organic light-emitting diodes[J].Advanced Functional Materials,2016,26(15):2545-2553.
[27] 叶新明,王远航,靳晴,等.新型超支化聚磷酰胺/聚磷酸铵协效阻燃聚丙烯的机理研究[J].化工新型材料,2018,46(5):170-172,176.
[28] Jiang X,Liu J,Xu L,et al.Disulfide-containing hyperbranched polyethylenimine derivatives via click chemistry for nonviral gene delivery[J].Macromolecular Chemistry & Physics,2011,212(1):64-71.
[29] 孙宁,李远,徐朝华,等.脂肪族多代超支化水性聚氨酯的制备与表征[J].化工新型材料,2013,41(6):81-83.
[30] Shen Y,He G,Guo Y,et al.Modified hyperbranched polyglycerol as dispersant for size control and stabilization of gold nanoparticles in hydrocarbons[J].Nanoscale Research Letters,2017,12(1):1-9.
[31] Dalvand A,Khoobi M,Nabizadeh R,et al.Reactive dye adsorption from aqueous solution on HPEI-modified Fe3O4 nanoparticle as a superadsorbent:characterization,modeling,and optimization[J].Journal of Polymers & the Environment,2018:26(8):3470-3483.
[32] Liu Y,Xu L,Liu X,et al.Hybrids of gold nanoparticles with core-shell hyperbranched polymers:synthesis,characterization,and their high catalytic activity for reduction of 4-nitrophenol[J].Catalysts,2016,6(1):3.
[33] Wang X,Wang B,Xing W,et al.Flame retardancy and thermal property of novel UV-curable epoxy acrylate coatings modified by melamine-based hyperbranched polyphosphonate acrylate[J].Progress in Organic Coatings,2014,77(1):94-100.
[34] Naik R B,Ratna D,Singh S K.Synthesis and characterization of novel hyperbranched alkyd and isocyanate trimer based high solid polyurethane coatings[J].Progress in Organic Coatings,2014,77(2):369-379.
[35] Mirshahi F,Bastani S,Sari M G.Studying the effect of hyperbranched polymer modification on the kinetics of curing reactions and physical/mechanical properties of UV-curable coatings[J].Progress In Organic Coatings,2016,90:187-199.
[36] Follmann H D M,Oliveira O N,Lazarin-Bidã3ia D,et al.Multifunctional hybrid aerogels:hyperbranched polymer-trapped mesoporous silica nanoparticles for sustained and prolonged drug release[J].Nanoscale,2018,10(4):1704-1715.
[37] Cao H,Chen C,Xie D,et al.A hyperbranched amphiphilic acetal polymer for pH-sensitive drug delivery[J].Polymer Chemistry,2018,9(2):169-177.
[38] Zhao J,Li D,Han H,et al.Hyperbranched zwitterionic polymer-functionalized underwater superoleophobic microfiltration membranes for oil-in-water emulsion separation[J].Langmuir,2019,35(7):2630-2638.
[39] Zhang L W,Hua J R,Zhu W J,et al.Flocculation performance of hyperbranched polyethyleneimine-grafted-cellulose in wastewater treatment[J].ACS Sustainable Chemistry & Engineering,2018,6(2):1592-1601.
[40] Pu W F,Liu R,Wang K Y,et al.Water-soluble core-shell hyperbranched polymers for enhanced oil recovery[J].Industrial & Engineering Chemistry Research,2015,54(3):798-807.
[41] Du D,Pu W,Tang Z J,et al.Solution properties and displacement characteristics of core-shell hyperbranched associative polyacrylamide for enhanced oil recovery[J].Energy & Fuels,2018,32(8):8154-8166.
基金资助
国家自然科学基金(21603193);河南省科技攻关计划项目(172102210546);郑州轻工业学院博士启动基金项目(2015BSJJ045)
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